In computer networking, CSMA/CA belongs to a class of protocols called multiple access methods. CSMA/CA stands for: Carrier Sense Multiple Access With Collision Avoidance. In CSMA, a station wishing to transmit has to first listen to the channel for a predetermined amount of time so as to check for any activity on the channel. If the channel is sensed "idle" then the station is permitted to transmit. If the channel is sensed as "busy" the station has to defer its transmission. This is the essence of both CSMA/CA and CSMA/CD. In CSMA/CA (LocalTalk), once the channel is clear, a station sends a signal telling all other stations not to transmit, and then sends its packet. In Ethernet 802.3, the station continues to wait for a time, and checks to see if the channel is still free. If it is free, the station transmits, and waits for an acknowledgment signal that the packet was received.

Reference:
http://en.wikipedia.org/wiki/CSMA/CA
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